(Acetonitrile-N)(o-benzoquinone diimine-N,N ')chloro-trans-bis(triphenylphosphine-P)ruthenium(II) hexafluorophosphate 0.25-hydrate

Venegas-Yazigi, D; Mirza, H; Lever, ABP; Lough, AJ; Costamagna J; Latorre R.

Abstract

The Ru atom in the title compound, [RuCl(CH3CN){P(C6 H-5)(3)}(2){C6H4(NH)(2)}]PF6. 0.25H(2)O, has a six-coordinate octahedral geometry, with a trans arrangement of the triphenylphosphine groups. The asymmetric unit contains two complex molecules and a partially occupied water site. Principal dimensions include Ru-N 1.958 (4)-2.044 (5), Ru-P 2.3897 (16)-2.4092 (15), and Ru-Cl 2.4280 (15) and 2.4295 (16) Angstrom.

Más información

Título según WOS: (Acetonitrile-N)(o-benzoquinone diimine-N,N ')chloro-trans-bis(triphenylphosphine-P)ruthenium(II) hexafluorophosphate 0.25-hydrate
Título de la Revista: ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
Volumen: 56
Editorial: WILEY-BLACKWELL PUBLISHING, INC
Fecha de publicación: 2000
Página de inicio: E247
Página final: E248
Idioma: English
URL: http://scripts.iucr.org/cgi-bin/paper?S0108270100006314
Notas: ISI