(Acetonitrile-N)(o-benzoquinone diimine-N,N ')chloro-trans-bis(triphenylphosphine-P)ruthenium(II) hexafluorophosphate 0.25-hydrate
Abstract
The Ru atom in the title compound, [RuCl(CH3CN){P(C6 H-5)(3)}(2){C6H4(NH)(2)}]PF6. 0.25H(2)O, has a six-coordinate octahedral geometry, with a trans arrangement of the triphenylphosphine groups. The asymmetric unit contains two complex molecules and a partially occupied water site. Principal dimensions include Ru-N 1.958 (4)-2.044 (5), Ru-P 2.3897 (16)-2.4092 (15), and Ru-Cl 2.4280 (15) and 2.4295 (16) Angstrom.
Más información
Título según WOS: | (Acetonitrile-N)(o-benzoquinone diimine-N,N ')chloro-trans-bis(triphenylphosphine-P)ruthenium(II) hexafluorophosphate 0.25-hydrate |
Título de la Revista: | ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS |
Volumen: | 56 |
Editorial: | WILEY-BLACKWELL PUBLISHING, INC |
Fecha de publicación: | 2000 |
Página de inicio: | E247 |
Página final: | E248 |
Idioma: | English |
URL: | http://scripts.iucr.org/cgi-bin/paper?S0108270100006314 |
Notas: | ISI |