Aqueous photopolymerization with visible-light photoinitiators: Acrylamide polymerization photoinitiated with a phenoxazine dye/amine system

Villegas, L; Encinas, MV; Rufs, AM; Bueno, C; Bertolotti, S; Previtali, CM

Abstract

We studied the photoinduced electron-transfer polymerization of acrylamide with, as a visible-light initiator, the heterocycle-N-oxide resazurin in the presence of triethanolamine. The irradiation of resazurin produces resorufin, which also absorbs in the visible region. Both phenoxazine dyes in the presence of the amine are efficient photoinitiators of acrylamide polymerization in an aqueous medium. The polyerization rates were measured at several amine concentrations. These values increase with the amine concentration, reaching a maximum value; further amine addition slightly decreases the polymerization rate. Time-resolved photolysis studies of the dyes were carried out under the polymerization conditions. The quenching of the dye excited states by the amine was analyzed with static-fluorescence and laser-flash photolysis. These data were used for fitting curves of the polymerization rate versus the amine concentration, and it was concluded that the interaction of triplet excited dyes with the amine leads to acrylamide polymerization.

Más información

Título según WOS: Aqueous photopolymerization with visible-light photoinitiators: Acrylamide polymerization photoinitiated with a phenoxazine dye/amine system
Título según SCOPUS: Aqueous photopolymerization with visible-light photoinitiators: Acrylamide polymerization photoinitiated with a phenoxazine dye/amine system
Título de la Revista: JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
Volumen: 39
Número: 23
Editorial: John Wiley & Sons Inc.
Fecha de publicación: 2001
Página de inicio: 4074
Página final: 4082
Idioma: English
URL: http://doi.wiley.com/10.1002/pola.10059
DOI:

10.1002/pola.10059

Notas: ISI, SCOPUS