Abstract

The phase behavior of blends containing Poly(N-1-alkyl itaconamic acids) (PNAIA) with Poly(2-vinylpyrindine) (P2VPy) and Poly(4-vinylphenol) (P4VPh) were analyzed by Diferential Scanning Calorimetry (DSC) and Fourier Transform Infrared Spectroscopy (FTIR). Miscibility over the whole range of compositions is observed in both systems. All the blends show thermograms exhibiting distinct single glass transition temperatures (Tg), which are intermediate to those of the pure components. The Calorimetric Analysis using Gordon Taylor, Couchman, and Kwei treatments allows conclusion that interactions between the components is favorable to the miscibility. FTIR analysis of the blends suggests that the driving force for miscibility is hydrogen bonding formation. The variation of the absorptions of the carbonyl groups of PNAIA and the hydroxyl groups of P4VPh allows one to attribute the miscibility to weak acid base like interactions. © 2002 Wiley Periodicals, Inc. J. Appl. Polym. Sci.