Single-molecule magnets: control by a single solvent molecule of Jahn-Teller isomerism in [Mn12O12(O2CCH2But)(16)(H2O)(4)]

Soler, M; Wernsdorfer, W; Sun, ZM; Huffman, JC; Hendrickson, DN; Christou, G

Abstract

Faster- and slower-relaxing versions of the title Mn-12 compound have been obtained in pure forms that crystallize in the same space group and differ only in the identity of one lattice solvent molecule; solvent loss causes isomerization from the faster- to the slower-relaxing form.

Más información

Título según WOS: ID WOS:000186492000013 Not found in local WOS DB
Título de la Revista: CHEMICAL COMMUNICATIONS
Número: 21
Editorial: ROYAL SOC CHEMISTRY
Fecha de publicación: 2003
Página de inicio: 2672
Página final: 2673
DOI:

10.1039/b306246e

Notas: ISI