Abstract

A coordination polymer is fully exfoliated by solvent‐assisted interaction only. The soft‐delamination process results from the structure of the starting material, which shows a layered structure with weak layer‐to‐layer interactions and cavities with the ability to locate several solvents in an unselective way. These results represent a significant step forward towards the production of structurally designed one‐molecule thick 2D materials with tailored physico‐chemical properties.