Adsorption mechanism of chromium(III) using biosorbents of Jatropha curcas L.

Goncalves, Affonso Celso, Jr.; Nacke, Herbert; Schwantes, Daniel; Campagnolo, Marcelo Angelo; Miola, Alisson Junior; Teixeira Tarley, Cesar Ricardo; Dragunski, Douglas Cardoso; Cajamarca Suquila, Fabio Antonio

Abstract

The removal of Cr3+ from water solutions by biosorbents from the rind, endosperm, and endosperm + episperm of the Jatropha curcas was evaluated. Adsorption tests were performed in batch systems for evaluating the influence of the solution's pH, adsorbent mass, contact time, initial Cr3+ concentrations, and solution temperature during the adsorption process. Kinetic, adsorption isotherm, and thermodynamic studies were performed to investigate the mechanisms that control adsorption. Ideal conditions for the adsorption process included pH of the solution of 5.5 and 8 g L-1 adsorbent mass, within 60 min time contact between adsorbent and adsorbate. Maximum adsorption capacities by Langmuir model for rind, endosperm, and endosperm + episperm of the J. curcas were, respectively, 22.11, 18.20, and 22.88 mg g(-1), with the occurrence of chemosorption in mono and multilayers. Results show that the biosorbents obtained from J. curcas have a high potential to recuperate Cr3+ from contaminated water sources.

Más información

Título según WOS: ID WOS:000409962200023 Not found in local WOS DB
Título de la Revista: ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
Volumen: 24
Número: 27
Editorial: SPRINGER HEIDELBERG
Fecha de publicación: 2017
Página de inicio: 21778
Página final: 21790
DOI:

10.1007/s11356-017-9749-z

Notas: ISI