Alkynes hydrogenation over Pd-supported catalysts

Marin-Astorga, N; Pecchi G.; Fierro, JLG; Reyes, P

Abstract

The liquid-phase stereoselective hydrogenation of phenyl alkyl acetylenics at 298 K and atmospheric pressure on Pd-supported catalysts has been studied. The catalysts were prepared by impregnation of Pd(acac)2 precursor (1 wt% of Pd) on different siliceous substrates such as amorphous SiO 2, mesoporous MCM-41 and silylated MCM-41. The poisoning effect of lead incorporation on the supported palladium was also studied. All the catalysts displayed high selectivity to cis-alkene isomer, with Pd/MCM-41 being the most active catalyst. Deliberately adding lead to the base, palladium catalysts underwent changes in the selectivity to cis-alkene isomer and a significant drop in the activity. All the solids were characterized by nitrogen adsorption-desorption isotherms at 77 K, TGA, TPR, H2 and CO chemisorption, XRD, XPS, and TEM.

Más información

Título según WOS: Alkynes hydrogenation over Pd-supported catalysts
Título según SCOPUS: Alkynes hydrogenation over Pd-supported catalysts
Título de la Revista: CATALYSIS LETTERS
Volumen: 91
Número: 01-feb
Editorial: Springer
Fecha de publicación: 2003
Página de inicio: 115
Página final: 121
Idioma: English
URL: http://link.springer.com/10.1023/B:CATL.0000006326.07708.04
DOI:

10.1023/B:CATL.0000006326.07708.04

Notas: ISI, SCOPUS