Adsorption of Ru, Ce and Eu radionuclides within naturally precipitated polycrystalline calcium carbonate under acidic environment

Sanwal, Jaishri; Dudwadkar, Nilesh L.; Thirumurugan, Arun; Tripathi, Subhash C.; Gandhi, P. M.; Satyam, P. V.; Sengupta, Pranesh

Abstract

Ru-106, Ce-144 and Eu152+154 radiotracers sorption experiments (pH: 1-6) have been carried out with polycrystalline columnar/microcrystalline calcite and aragonite obtained from a stalagmite of Dharamjali cave, India. The different domains of the sample were powdered and thoroughly studied using electron microscopic and X-ray spectroscopic techniques. Both Ru-106 and Ce-144 exhibited higher sorption within calcite varieties compared to aragonite and increased with rising pH, while it showed reverse relation in case of Eu152+154. Further, it is noted that aragonite offers the highest K (d) values for Eu152+154, whereas Ru-106 and Ce-144 prefer calcite.

Más información

Título según WOS: ID WOS:000379626500034 Not found in local WOS DB
Título de la Revista: JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
Volumen: 309
Número: 2
Editorial: Springer
Fecha de publicación: 2016
Página de inicio: 751
Página final: 760
DOI:

10.1007/s10967-015-4672-6

Notas: ISI