Selective acylation of 4,5-diamino-9,9 '-dimethylxanthene through an aggregation effect
Abstract
The proximity of the 4,5-diamino groups in a 9,9'-dimethylxanthene skeleton provides unique reactivity due to aggregation effects. While treatment with 1 equiv of an isocyanate yields the diurea and starting material, under similar conditions, Boc(2)O provides essentially only the monocarbamoyl derivative. (C) 2007 Elsevier Ltd. All rights reserved.
Más información
Título según WOS: | ID WOS:000253170200011 Not found in local WOS DB |
Título de la Revista: | TETRAHEDRON LETTERS |
Volumen: | 49 |
Número: | 5 |
Editorial: | PERGAMON-ELSEVIER SCIENCE LTD |
Fecha de publicación: | 2008 |
Página de inicio: | 790 |
Página final: | 793 |
DOI: |
10.1016/j.tetlet.2007.11.189 |
Notas: | ISI |