Selective acylation of 4,5-diamino-9,9 '-dimethylxanthene through an aggregation effect
Abstract
The proximity of the 4,5-diamino groups in a 9,9'-dimethylxanthene skeleton provides unique reactivity due to aggregation effects. While treatment with 1 equiv of an isocyanate yields the diurea and starting material, under similar conditions, Boc(2)O provides essentially only the monocarbamoyl derivative. (C) 2007 Elsevier Ltd. All rights reserved.
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| Título según WOS: | ID WOS:000253170200011 Not found in local WOS DB |
| Título de la Revista: | TETRAHEDRON LETTERS |
| Volumen: | 49 |
| Número: | 5 |
| Editorial: | PERGAMON-ELSEVIER SCIENCE LTD |
| Fecha de publicación: | 2008 |
| Página de inicio: | 790 |
| Página final: | 793 |
| DOI: |
10.1016/j.tetlet.2007.11.189 |
| Notas: | ISI |