Chromogenic charge transfer cleft-type tetrahydrobenzoxanthene enantioselective receptors for dinitrobenzoylamino acids

Oliva, AI; Simon, L.; Muniz, FM; Sanz, F; Ruiz-Valero, C; Moran, JR

Abstract

A combination of a benzoxanthene cleft-type receptor with an electron-rich aromatic ring capable of establishing charge-tranfer interactions provides enantioselective receptors for dinitrobenzoylamino acids. Racemic mixtures of the receptor can be resolved with TLCs impregnated with the guest. The structure of the complexes has been established in an X-ray study. Enantiomeric amino acids provide complexes with different colors.

Más información

Título según WOS: ID WOS:000224143000044 Not found in local WOS DB
Título de la Revista: Journal of Organic Chemistry
Volumen: 69
Número: 20
Editorial: American Chemical Society
Fecha de publicación: 2004
Página de inicio: 6883
Página final: 6885
DOI:

10.1021/jo049113h

Notas: ISI