Enantioselective chromenone benzoxazole receptor for glutamic acid and its derivatives

HERNANDEZ, JV; Oliva, AI; Simon, L.; Muniz, FM; Mateos, AA; Moran, JR

Abstract

Combination of a binaphthyl unit with chromenone benzoxazole fragments provided a chiral receptor that is enantioselective for glutamic acid and its derivatives. The receptor racemic mixture was resolved by TLCs impregnated with (R,R)-thiodilactic acid. High association constants were measured for dansylglutamic acid, using a fluorescent method. This receptor can be used for the resolution of the tosylglutamic acid racemic mixture.

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Título según WOS: ID WOS:000185343200046 Not found in local WOS DB
Título de la Revista: Journal of Organic Chemistry
Volumen: 68
Número: 19
Editorial: American Chemical Society
Fecha de publicación: 2003
Página de inicio: 7513
Página final: 7516
DOI:

10.1021/jo0347157

Notas: ISI