Abstract

the influence of a nonionic surfactant compound (sorbitan monooleate) on the coupled transport of Cu(II) ions in a hollow fiber-type solid supported liquid membrane extractor was studied. The acid compound 5-nonylsalicylaldoxime was used as carrier extractant. The experimental results indicate that the surfactant presents a remarkable interfacial activity, higher than those shown by the carrier extractant which would adsorb at the inteface too. From the experimental results it were calculated for the surfactant the interfacial area occupied by mol, the adsorption equilibrium constant and their critical micelle concentration. Results of extraction equilibrium experiments indicate that Span-80 itself did not extract copper and that Cu(II) extraction is enhanced as the acidity of feed aqueous solution decreases. It was found that the surfactant accelerates the permeability of metal in runs carried out using a higher concentration of Span-80 and when a pH value of 2.5 was adjusted for feed solution. In such condition transport rate of metal through liquid membrane would be controlled by the diffusion of chemical species in it. Furthermore, apparent permeability of copper is enhanced when the content of extractant at liquid membrane is augmented. A preliminary simplified mechanism of metal permeation through the liquid membrane is proposed. The mechanism is based on an heterogeneous interfacial reaction accelerated in the presence of the nonionic surfactant