Synthesis and properties of PdSn/Al2O3 and PdSn/SiO2 prepared by solvated metal atom dispersed method

Cardenas, G; Oliva R.; Reyes, P; Rivas BL

Abstract

A series of solvated metal atom dispersion (SMAD) catalysts: Pd/SiO2, Pd/Al2O3, Sn/SiO2, Sn/Al2O3, PdxSny/SiO2 and PdxSny/Al2O3. It was prepared by simultaneous evaporation of Pd and Sn. The metals were co-deposited at 77 K using acetone, 2-propanol and THF to produce colloids "in situ" all the supported catalyst were characterized by chemisorption, transmission electron microscopy (TEM), thermogravimetric analysis (TGA) and TPR. This series of catalyst were tested for crotonaldehyde hydrogenation in gas phase to obtain crotyl alcohol. © 2002 Elsevier Science B.V. All rights reserved.

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Título según WOS: Synthesis and properties of PdSn/Al2O3 and PdSn/SiO2 prepared by solvated metal atom dispersed method
Título según SCOPUS: Synthesis and properties of PdSn/Al2O3 and PdSn/SiO2 prepared by solvated metal atom dispersed method
Título de la Revista: JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
Volumen: 191
Número: 1
Editorial: Elsevier
Fecha de publicación: 2003
Página de inicio: 75
Página final: 86
Idioma: English
URL: http://linkinghub.elsevier.com/retrieve/pii/S1381116902003333
DOI:

10.1016/S1381-1169(02)00333-3

Notas: ISI, SCOPUS