Excited States versus Reaction Intermediates as Active Species in Photoinduced Redox Reactions of Cyrhetrenyl and Ferrocenyl Chalcones: A 351 nm Flash Photolysis Study

Maldonado T.; Ferraudi G.; Lappin A.G.; Godoy F.

Abstract

The photoinduced redox reactions of two organometallic chalcones: tram, E, (eta(5)-C5H4 C(O)CH=CH-4-benzo-15-crown-5)Re(CO)(3), 1, and tram, E, (eta(5)-C5H4C(O)CH=CH-4-benzo-15-crown-5)Fe(eta(5)-C5H4C(O)CH=CH-4-benzo-15-crown-5), 2, were investigated in fluid solution using the flash photolysis technique. For a better understanding of the photoinduced redox processes of these organometallic chalcones, an electron donor, triethylamine (TEA), and an electron acceptor, methylviologen dichloride (MVCl2), were chosen. Two parallel reaction paths for the decay of the intermediate 1-I, that is, the anion radical of 1, were observed in the presence of TEA. One generates a radical anion, while the other reaction path produces the Z isomer. Instead, the photoinduced reaction of 2 with TEA in MeOH generates an intense absorption band at lambda(max) = 660 nm, which is attributed to a 2-I center dot MeOH adduct. The oxidative process between 1-I and MV2+ in CH3CN generates transient spectra consistent with the formation of the radical cation MV center dot+. In contrast, the photoinduced reaction between 2 and MV2+ showed that the generation of MV center dot+ occurs through a complex mechanism. MV center dot+ is formed in two steps where the first one is the formation of an adduct between the long-lived metal-to-ligand charge transfer (MLCT) (Fe -> Chalcone) excited state and MV2+. These results have shown that intermediates 1-I and 2-I can function as photo-oxidants and photoreductants better than the chalcone short-lived excited states.

Más información

Título según WOS: Excited States versus Reaction Intermediates as Active Species in Photoinduced Redox Reactions of Cyrhetrenyl and Ferrocenyl Chalcones: A 351 nm Flash Photolysis Study
Título según SCOPUS: Excited States versus Reaction Intermediates as Active Species in Photoinduced Redox Reactions of Cyrhetrenyl and Ferrocenyl Chalcones: A 351 nm Flash Photolysis Study
Título de la Revista: JOURNAL OF PHYSICAL CHEMISTRY A
Volumen: 123
Número: 43
Editorial: AMER CHEMICAL SOC
Fecha de publicación: 2019
Página de inicio: 9274
Página final: 9281
Idioma: English
DOI:

10.1021/acs.jpca.9b06603

Notas: ISI, SCOPUS