Selective liquid-liquid extraction of molybdenum (VI) and rhenium (VII) from a synthetic pregnant leach solution: Comparison between extractants and diluents

Quijada-Maldonado E.; Allain A.; Pérez B.; Merlet G.; Cabezas R.; Tapia R.; Romero J.

Abstract

A study on the selective solvent extraction (SX) of Molybdenum (Mo) and Rhenium (Re) from a synthetic pregnant leach solution (PLS) has been carried out using two diluents: kerosene and the ionic liquid (IL) 1-octyl-3-methylimidazolium bis(trifluoromethylsufonyl)imide ([omim] [Tf2N]) and two extractants: di(ethylhexyl) phosphoric acid (D2EHPA) and the IL trioctylmethylammonium bis(2-ethylhexyl) phosphinate [TOMA] [D2EHP]. It can be concluded that the D2EHPA extractant in kerosene achieved selective Mo-Re extractions, times was achieved when replacing kerosene with [omim] [Tf2N], but this time with low extraction percentages. This work shows how ionic liquids, as extractants or diluents, can improve the selective separations in industrial metal extractions.

Más información

Título según WOS: Selective liquid-liquid extraction of molybdenum (VI) and rhenium (VII) from a synthetic pregnant leach solution: Comparison between extractants and diluents
Título según SCOPUS: Selective liquid-liquid extraction of molybdenum (VI) and rhenium (VII) from a synthetic pregnant leach solution: Comparison between extractants and diluents
Volumen: 145
Fecha de publicación: 2020
Idioma: English
DOI:

10.1016/j.mineng.2019.106060

Notas: ISI, SCOPUS