An efficient and eco-friendly method for the thiol-Michael addition in aqueous solutions using amino acid ionic liquids (AAILs) as organocatalysts
Keywords: michael addition
Abstract
A series of amino-acid based ionic liquids (Bmim[AA]s) have been synthesized and evaluated as catalysts, in aqueous solution. The results of a kinetic study of the thiol-Michael reaction of L-Cysteine with trans-β-nitrostyrene demonstrated the advantages of using (Bmim[AA]s) as organocatalysts. The benefits include high rate constants; mild reaction conditions; and, a reusable catalyst, which leads to a simple and efficient method for these important kinds of reactions
Más información
Título de la Revista: | PURE AND APPLIED CHEMISTRY |
Volumen: | 92 |
Editorial: | De Gruyter |
Fecha de publicación: | 2020 |
Página de inicio: | 97 |
Página final: | 106 |
Idioma: | english |
DOI: |
10.1515/PAC-2019-0212 |
Notas: | ISI |