Comparative study of two chemically isostructural polymers: [Cu-2(VO2)(HPO4)(2)(NO3)(bpy)(2)]center dot 2H(2)O/H3PO4 (bpy is 2,2 '-bipyridine)

Moreno Y.; Vega A.; Spodine, E.; Ushak, E; Baggio R.

Abstract

The crystal structure of copper compound, [Cu2(VO 2)(HPO4)2 (NO3)(bpy)2].X was studied. These chemically isostructural systems were obtained by hydrothermal methods, which differ in the solvate molecules stabilizing the structures. The compound were stabilized by different solvates, two crystallization water molecules in (I) and a phosphoric acid molecule in (II). This provides the main structural differences through the diversity of interchain in which they serve as bridges.

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Título según WOS: Comparative study of two chemically isostructural polymers: [Cu-2(VO2)(HPO4)(2)(NO3)(bpy)(2)]center dot 2H(2)O/H3PO4 (bpy is 2,2 '-bipyridine)
Título según SCOPUS: Comparative study of two chemically isostructural polymers: [Cu 2(VO2)-(HPO4)2(NO 3)(bpy)2]·2H2O/H3PO 4 (bpy is 2,2?-bipyridine)
Título de la Revista: ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
Volumen: 60
Número: 10
Editorial: WILEY-BLACKWELL PUBLISHING, INC
Fecha de publicación: 2004
Página de inicio: M484
Página final: M488
Idioma: English
URL: http://scripts.iucr.org/cgi-bin/paper?S0108270104019687
DOI:

10.1107/S0108270104019687

Notas: ISI, SCOPUS