Single-crystal anisotropic proton conductivity in the clathrate of the hvdrogen-diquinuclidine ion inserted in a polyanionic thiourea-chloride matrix

Yutronic, N; Merchan, J; Jara P.; Manriquez, V.; Wittke, O; Gonzalez G.

Abstract

The anisotropic proton conductivity of a large-sized single crystal of the supramolecular, commensurate host-guest inclusion compound constituted by a polyanionic thiourea-chloride matrix defining channels in which the diquinuclidinium cations [Q2H]+ are hosted is reported. Specimens in the millimetre scale display an anisotropy factor of about 100, with electrical conductivities along molecular channels of the order of 10 -4 S cm-1 at room temperature.

Más información

Título según WOS: Single-crystal anisotropic proton conductivity in the clathrate of the hvdrogen-diquinuclidine ion inserted in a polyanionic thiourea-chloride matrix
Título según SCOPUS: Single-crystal anisotropic proton conductivity in the clathrate of the hydrogen-diquinuclidine ion inserted in a polyanionic thiourea-chloride matrix
Título de la Revista: SUPRAMOLECULAR CHEMISTRY
Volumen: 16
Número: 6
Editorial: TAYLOR & FRANCIS LTD
Fecha de publicación: 2004
Página de inicio: 411
Página final: 414
Idioma: English
URL: http://www.tandfonline.com/doi/abs/10.1080/10610270412331286003
DOI:

10.1080/10610270412331286003

Notas: ISI, SCOPUS