CYCLIC VOLTAMMETRY OF 1-(n-HEXYL)-3-METHYL-5-PYRAZOLONE-BASED ENAMINES AND THEIR CHLOROMANGANESE(III) AND NITRIDOMANGANESE(V) COMPLEXES
Abstract
In this publication we are reporting for the first time on examples of the redox behavior of enamines and complexes derived from 1-alkylpyrazolones. Cyclic voltammetry experiment was performed on three enamines derived from 4-acyl-1-(n-hexyl)-3-methylpyrazol-5-ol and their chloromanganese(III) and nitridomanganese(V) complexes. The ligands have an irreversible oxidation potential of 1.1 V. Chloromanganese(III) complexes are quasi-reversible with an E1/2 of
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Título según WOS: | Cyclic voltammetry of 1-(n-hexyl)-3-methyl-5-pyrazolone-based enamines and their chloromanganese(III) and nitridomanganese(V) complexes |
Título según SCIELO: | CYCLIC VOLTAMMETRY OF 1-(n-HEXYL)-3-METHYL-5-PYRAZOLONE-BASED ENAMINES AND THEIR CHLOROMANGANESE(III) AND NITRIDOMANGANESE(V) COMPLEXES |
Título de la Revista: | Journal of the Chilean Chemical Society |
Volumen: | 50 |
Número: | 3 |
Editorial: | SOC CHILENA QUIMICA |
Fecha de publicación: | 2005 |
Página de inicio: | 575 |
Página final: | 580 |
Idioma: | English |
DOI: |
10.4067/S0717-97072005000300009 |
Notas: | ISI, SCIELO |