Photophysics of tungsten–benzylidyne complexes derived from s-indacene: synthesis, characterization and DFT studies

Morales-Verdejo, Cesar; Zarate, Ximena; Schott, Eduardo; Correa, Sebastian; Martinez Diaz, Ivan

Abstract

The photophysics of the mono- and homobimetallic complexes of tungsten–benzylidyne derived from s-indacene have been examined by using absorption and emission. Theoretical calculations of these compounds were carried out to gain further understanding of these novel molecular systems. Consistent with this prediction, each of the complexes displays a weak, mid-visible absorption band which is attributed to the d → π* transition. The tungsten complexes also exhibit luminescence with a lifetime in the 5–6 ns regime.

Más información

Título de la Revista: JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
Volumen: 5
Editorial: Elsevier
Fecha de publicación: 2015
Página de inicio: 25594
Página final: 25602
Idioma: inglés
URL: https://pubs.rsc.org/en/content/articlelanding/2015/ra/c4ra16874g/unauth#!divAbstract
DOI:

https://doi.org/10.1039/C4RA16874G

Notas: WOS, ISI