Ruthenium(II)–carbonyl complexes containing two N-monodentate 1,8-naphthyridine ligands: active catalysis in transfer hydrogenation reactions

Juana Guajardo, Andres Ibanez, Veronique Guerchais, Andres Vega, Sergio Moya and Pedro Aguirre*

Keywords: ruthenium complexes

Abstract

The reaction of 2-aminonicotinaldehyde with 2- or 4-methoxyacetophenone in basic media leads to the new ligands 2-(4-methoxyphenyl)-1,8-naphthyridine and 2-(2-methoxyphenyl)-1,8-naphthyridine, respectively, in high yield. The reaction of these naphthyridine derivatives with [RuCl2(CO)2]n leads to the respective complexes cis-dicarbonyldichloridobis[2-(4-methoxyphenyl)-1,8-naphthyridine- N8]ruthenium(II) and cis-dicarbonyldichloridobis[2-(2-methoxyphenyl)- 1,8-naphthyridine-N8]ruthenium(II), both [RuCl2(C15H12N2O)2(CO)2], in good yield. Both ruthenium(II) complexes display a slightly distorted octahedron with two cis carbonyl, two cis chloride and two cis naphthyridine ligands, the latter coordinated in a monodentate fashion through the N atom in the 8-position. Both complexes exhibit a moderate catalytic activity in the hydrogen-transfer reaction from propan-2-ol to acetophenone in the presence of a base, with 100% selectivity. 1.

Más información

Título de la Revista: ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY
Volumen: C74
Editorial: INT UNION CRYSTALLOGRAPHY
Fecha de publicación: 2018
Página de inicio: 1547
Página final: 1552
Idioma: ingles
Financiamiento/Sponsor: FONDECYT