Abstract

Powder magnetite was analyzed in situ via Mossbauer with temperatures ranging from 170 K up to 900 K. Hyperfine fields of the tetrahedral and octahedral sites of magnetite as well as the corresponding average field were followed as a function of temperature in order to elucidate the critical behavior of magnetite at around the Curie temperature. Results evidence a progressive collapse of the Mossbauer spectra onto a singlet-type line at a critical temperature of around 870 K characterized by a critical exponent beta = 0.28(2) for the hyperfine field. In order to describe such temperature dependence of the hyperfine field, a Monte Carlo-Metropolis simulation based on a stoichiometric magnetite and an Ising model with nearest magnetic neighbor interactions was also carried Out. In the model, we have taken into account anti ferromagnetic and ferromagnetic interactions depending on the involved ions. A discussion about the critical behavior of magnetite and a comparison between the hyperfine field obtained via Mossbauer and the magnetization obtained via Monte Carlo is finally presented.