DENITROGENATION BY ADSORPTION OF PYRIDINE ON NI/SUPPORT ADSORBENTS

Peralta, Cecilia; Camu, Esteban; Bassi, R.; Villarroel, Mirza; Ojeda, Juan; Baeza, Patricio

Abstract

In this work we have carried out the adsorption of pyridine using three different supports (activated carbon, SiO2 and gamma-Al2O3). After choosing the best support, due to its higher adsorption capacity, we have impregnated the support with nickel at three different concentrations (2, 4 and 6% w/w) by wet impregnation to study the adsorption of pyridine by pi-complexation. All the samples (supports and adsorbents) were characterized by N-2 adsorption-desorption by the BET method and electrophoretic migration. The experimental results, for the three different supports, show that the adsorption capacity is better for gamma-Al2O3, due to its higher isoelectric point. With the incorporation of nickel, no better adsorption capacities are observed, due that the nickel incorporation diminish the zero point charges of the adsorbents.

Más información

Título según WOS: DENITROGENATION BY ADSORPTION OF PYRIDINE ON NI/SUPPORT ADSORBENTS
Título de la Revista: Journal of the Chilean Chemical Society
Volumen: 61
Número: 4
Editorial: 2013
Fecha de publicación: 2016
Página de inicio: 3211
Página final: 3213
DOI:

10.4067/S0717-97072016000400012

Notas: ISI