(2S,R-S)-6-Phenyl-1-(p-tolylsulfinyl)-hexa-3(E),5(E)-dien-2-ol

Donoso-Tauda, O; Escobar, CA; Araya-Maturana, R; Vega A.

Abstract

The molecule of the title compound, C19H20O 2S, corresponds to a chiral sulfinyldienol with two stereogenic centres, viz. the C atom susbtituted by the hydroxy group and the sulflnyl S atom. The molecule displays a V-shape in the solid state. The dihedral angle defined by the least-squares planes of the aromatic rings is 72.9 (1)°. The packing pattern exhibits the following intermolecular hydrogen bonds: one O-H⋯O [H⋯O = 1.98 Å, O⋯O = 2.785 (4) Å and O-H⋯O = 166°] and two C-H⋯O [H⋯O = 2.58 and 2.60 Å, C⋯O = 3.527(5) and 3.347 (5) Å, and C-H⋯O = 164 and 134°]. These define a chain along b. © 2006 International Union of Crystallography.

Más información

Título según WOS: (2S,R-S)-6-Phenyl-1-(p-tolylsulfinyl)-hexa-3(E),5(E)-dien-2-ol
Título según SCOPUS: (2S,RS)-6-phenyl-1-(p-tolylsulfinyl)-hexa-3(E),5(E)-dien-2-ol
Título de la Revista: ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY
Volumen: 62
Número: 10
Editorial: WILEY-BLACKWELL
Fecha de publicación: 2006
Página de inicio: O631
Página final: O632
Idioma: English
URL: http://scripts.iucr.org/cgi-bin/paper?S0108270106036171
DOI:

10.1107/S0108270106036171

Notas: ISI, SCOPUS