(1 alpha, 12 alpha)-Ethyl 15-ethoxy-4-hydroxy-2-oxo-9-oxatetracyclo[10.2.2.0(1,10).0(3,8)]hexadeca-4,6,8,13-tetraene-13-carboxylate

Heredia-Moya, J; Krohn, K; Florke, U; Araya-Maturana, R

Abstract

(E)-Ethyl 3-(4-oxo-4H-chromen-3-yl)acrylate reacts in a Domino reaction with ethyl vinyl ether via intermediates to give the title bridged compound, C20H22O6, and by-products. The conformation of the carboxylate group in the molecular structure is determined by intramolecular hydrogen bonds. In the crystal structure, molecules are linked via intermolecular C-H⋯O hydrogen bonds. © 2006 International Union of Crystallography. All rights reserved.

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Título según WOS: (1 alpha, 12 alpha)-Ethyl 15-ethoxy-4-hydroxy-2-oxo-9-oxatetracyclo[10.2.2.0(1,10).0(3,8)]hexadeca-4,6,8,13-tetraene-13-carboxylate
Título según SCOPUS: (1a, 12a)-ethyl 15-ethoxy-4-hydroxy-2-oxo-9-oxatetracyclo[10.2. 2.01,10.03,8]hexadeca4,6,8,13-tetraene-13-carboxylate
Título de la Revista: ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
Volumen: 62
Número: 9
Editorial: WILEY-BLACKWELL
Fecha de publicación: 2006
Página de inicio: O3636
Página final: O3638
Idioma: English
URL: http://scripts.iucr.org/cgi-bin/paper?S1600536806029175
DOI:

10.1107/S1600536806029175

Notas: ISI, SCOPUS