Article ISI SCOPUS
ORGANOMETALLICS  (2006)

Experimental and theoretical evidence for the first example of an organolanthanide(II) compound having an indenyl ligand bonded to the metal through the benzo ring in eta(4) hapticity

Wang, SW; Tang, XF; Vega A.; Saillard, JY; Sheng, EH; Yang, GS; Zhou, SL; Huang, ZX

Abstract

The reaction of 2 equiv of C9H6-1-SiMe 3-3-CH2CH2-NC5H10 (2) with the ytterbium(III) amide [(Me3Si)2N] 3Yb-(μ-Cl)Li(THF)3 produced a novel ytterbium(II) complex with an indenyl ligand bonded to the metal via the benzo ring with η4 hapticity, (η4: η2η1-(C5H10NCH 2CH2C9H5SiMe3)Li(μ-Cl) ]Yb-(η5:η1-C5H10NCH 2CH2C9H5SiMe3) (1), as verified by a solid-state structure determination and theoretical calculations. © 2006 American Chemical Society.

Más información

Título según WOS: Experimental and theoretical evidence for the first example of an organolanthanide(II) compound having an indenyl ligand bonded to the metal through the benzo ring in eta(4) hapticity
Título según SCOPUS: Experimental and theoretical evidence for the first example of an organolanthanide(II) compound having an indenyl ligand bonded to the metal through the benzo ring in ?4 hapticity
Título de la Revista: ORGANOMETALLICS
Volumen: 25
Número: 10
Editorial: AMER CHEMICAL SOC
Fecha de publicación: 2006
Página de inicio: 2399
Página final: 2401
Idioma: English
URL: http://pubs.acs.org/doi/abs/10.1021/om0601192
DOI:

10.1021/om0601192
Notas: ISI, SCOPUS