A novel platform of using copper (II) complex with triazole-carboxilated modified as bidentated ligand SPCE for the detection of hydrogen peroxide in milk
Abstract
A screen-printed carbon electrode (SPCE) modified with copper (II) 1-(3-bromobenzyl)-5-methyl-1H-1,2,3-triazole-4-carboxylate [Cu(bmtc)(2)(H2O)] and was used as an electrochemical sensor of hydrogen peroxide. The material was characterised by crystal X-ray and cyclic voltammetry. The electrochemical behaviour of the modified electrode [Cu(bmtc)(2)(H2O)]/SPCE was evaluated against bare SPCE for the reduction of 1.0 mM H2O2 in phosphate buffer (pH = 7.0), where the modified electrode responded similar to -0.55 V even though the SPCE did not present response. On the other hand, analytical parameters such as reproducibility (2.7%), repeatability (2.6%), LOD (5.8 x 10(-7) mol L-1), selectivity (physiological substances) and stability were evaluated.
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Título según WOS: | A novel platform of using copper (II) complex with triazole-carboxilated modified as bidentated ligand SPCE for the detection of hydrogen peroxide in milk |
Título de la Revista: | JOURNAL OF ELECTROANALYTICAL CHEMISTRY |
Volumen: | 879 |
Editorial: | ELSEVIER SCIENCE SA |
Fecha de publicación: | 2020 |
DOI: |
10.1016/j.jelechem.2020.114763 |
Notas: | ISI |