One-step solution synthesis of a two-dimensional semiconducting covalent organometallic nanosheet via the condensation of boronic acid

Wang, Qijun; Yan, Jiahao; Xiao, Mingchao; Manoj, Devaraj; Zhong, Cheng; Lv, Qiying; Yang, Lite; Wu, Liangmei; Wang, Zhuoping; Bao, Lihong; Gao, Hongjun; Xiao, Fei; Jiang, Lang; Wang, Shuai

Abstract

In this work, a 2D covalent organometallic nanosheet (COMS) was designed and successfully synthesized through the one-step conjunction of a terpyridine-metal-terpyridine (TMT) sandwich coordinate motif with borate ester covalent heterocyclic (B3O3) linkage via the condensation of boronic acid. The obtained 2D COMS with a cobalt coordination center (2D COMS-Co) showed promising p-type semiconducting properties.

Más información

Título según WOS: ID WOS:000487104200048 Not found in local WOS DB
Título de la Revista: RSC ADVANCES
Volumen: 9
Número: 50
Editorial: ROYAL SOC CHEMISTRY
Fecha de publicación: 2019
Página de inicio: 29327
Página final: 29330
DOI:

10.1039/c9ra05806k

Notas: ISI