POLYCHELATES OF POLY(4-VINYLPYRIDINE) WITH Cu(II) AND Zn(II): SYNTHESIS,CHARACTERIZATION, AND SEMI-EMPIRICA CALCULATIONS

Seguel, GV; Rivas BL; Novas C.

Abstract

Polychelates of poly(4-vinyl pyridine) with metal acetates of Cu(II) and Zn(II) are synthesized. These compounds are characterized by elemental and thermal analysis, FT-IR and electronic spectroscopies in the d-d region of the spectrum. The influence of the nitrogen polymer ligand on the structure of metal acetates is studied. Semi-empirical calculations by PM3 method are done. To that the most stable polymer ligand conformations of the polychelates are employed. The electrostatic potential of the most stable polychelate structures is calculated

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Título según WOS: Polychelates of poly(4-vinylpyridine) with Cu(II) and Zn(II). Synthesis, characterization, and semi-empirica calculations
Título según SCOPUS: Polychelates of poly(4-vinylpyridine) with Cu(II) and Zn(II). Synthesis, characterization, and semi-empirica calculations
Título según SCIELO: POLYCHELATES OF POLY(4-VINYLPYRIDINE) WITH Cu(II) AND Zn(II): SYNTHESIS,CHARACTERIZATION, AND SEMI-EMPIRICA CALCULATIONS
Título de la Revista: Journal of the Chilean Chemical Society
Volumen: 51
Número: 1
Editorial: SOC CHILENA QUIMICA
Fecha de publicación: 2006
Página de inicio: 801
Página final: 807
Idioma: English
DOI:

10.4067/S0717-97072006000100009

Notas: ISI, SCIELO, SCOPUS