Article ISI
POLYMER BULLETIN  (2004)

Synthesis of UHMW-PE by a highly active homogeneous system: eta(5)-(C5H5)(2)Ti(eta(1)-OC(O)C6H5)(2)/MAO

Chirinos, J; Arevalo, J; Rajmankina, T; Morillo, A; Ibarra,D.; Bahsas, A; Parada, A

Abstract

The complex eta(5)-(C5H5)(2)Ti (eta(1)-OC(O)C6H5)(2) was synthesized and activated with MA0 for ethylene polymerization. The resultant polymer is UHMW-PE with a viscosimetric molecular weight of Mv = 6.8 x 10(6) to 0.7 x 10(6) g/mol dependent on the temperature of the reaction. The effects of the Al/Ti molar ratio and temperature of the reaction on the catalytic activity and polymer properties were studied.

Más información

Título según WOS: ID WOS:000221056100008 Not found in local WOS DB
Título de la Revista: POLYMER BULLETIN
Volumen: 51
Número: 5-6
Editorial: Springer
Fecha de publicación: 2004
Página de inicio: 381
Página final: 387
DOI:

10.1007/s00289-004-0237-5
Notas: ISI