Abstract

Using voltage-time responses and cyclic voltammetry, the initial stages of anodizing of Al-2.1 at.% Ag and Al-4 at.% Ag alloys are shown to depend upon the heat treatment of the alloys and the pre-treatment of the alloy surfaces. Chemical polishing of solution-treated alloys leads to relatively uniform anodic oxidation on a relatively smooth alloy surface, in the absence of significant effects of coarse, silver-rich intermetallics. In contrast, losses of current to oxygen generation arise for the roughened alloy surface from mechanical polishing. With ageing, secondary reactions at the relatively silver-rich intermetallics are more prevalent, although the effects on the voltage-time response depend upon the balance between processes occurring on the matrix and intermetallic regions, including film growth, oxygen generation within the anodic film, film damage due to release of oxygen, dissolution of silver species and re-growth of damaged film. © Springer-Verlag 2005.