Abstract

Deep eutectic solvents (DESs) have emerged as promising "green" solvents, but their successful industrial application requires relatively low viscosity. DESs prepared from choline chloride and glycols offer such a possibility. Viscosity and density are reported for a number of DESs obtained by mixing choline chloride and a glycol (ethylene glycol, 1,2-propanediol, 1,3-propanediol, and 1,4-butanediol). The measurements were performed at 101.3 kPa, at temperatures between 293.15 and 333.15 K, and for different mole ratios of glycol and choline chloride. The viscosity was measured with a capillary viscometer, while the density was measured by means of a vibrating U-tube densimeter. The density and viscosity data have expanded relative uncertainties of 0.2 and 2.0%, respectively, with a coverage factor of 2. The viscosity of pure glycols was modeled using the extended hard-sphere (EHS) model that has its basis in kinetic theory and the molecular description of the fluid. Each DES was treated as a binary mixture, and the EHS model was used, with a mole average mixing rule, to calculate its viscosity. The measured DES viscosity data were represented with an average absolute deviation of 1.4% and a maximum deviation of 7%.