Abstract

The efficiency of hydrogen peroxide in the regeneration of dimethyl sulphide (DMS) exhausted-activated carbons (ACs) is assessed in this study. Moreover, the influence of chemical surface composition is evaluated using six ACs (two commercial ACs and four chemically modified ACs) with different surface features. Chemical surface composition of ACs before and after different adsorption-regeneration cycles is assessed by temperature-programmed desorption coupled with mass spectroscopy (TPD-MS) and by diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS). Results reveal that up to a 60% of regeneration efficiency is attained, being more effective in the presence of ACs derived from Filtrasorb 300 AC sample. Experimental findings show that ACs with high content of basic oxygen-containing functional surface groups and mineral fraction are responsible to promote the catalytic decomposition of hydroxide peroxide, leading to a higher formation of hydroxyl radicals and to the observed increase in the regenerative oxidation of adsorbed DMS. However, a decrease in removal efficiency is related to an increase in the amounts of oxygen functionalities mainly in the form of strong acidic surface groups such as carboxylic acid anhydrides and carboxylic acids that shift the reaction mechanism from promoting the initiation of radical chain reactions to termination. Additionally, DRIFTS analyses indicate that after successive adsorption-regeneration cycles the fraction of organic molecules that remains adsorbed limits the access to active surface sites responsible for radical generation, reducing drastically the catalytic activity of ACs. (c) 2021 Institution of Chemical Engineers. Published by Elsevier B.V. All rights reserved.