Abstract

In this study, a novel method for calcium carbonate deposition in wood that increases carbon dioxide concentration and fire resistance is proposed. The method promoted the mineralization of radiata pine wood microstructure with calcium carbonate by using a process consisting in the vacuum impregnation of wood with a calcium chloride aqueous solution and the subsequent sequential diffusion of gaseous ammonium and carbon dioxide. In the most favorable conditions, the method yielded a weight gain of about 20 wt.% due to mineralization, which implied the accumulation of 0.467 mmol center dot g(-1) of carbon dioxide in the microstructure of wood. In addition, a weight gain of about 8% was sufficient to provide fire resistance to a level similar to that achieved by a commercially available fire-retardant treatment. The feasibility of retaining carbon dioxide directly inside the wood microstructure can be advantageous for developing wood products with enhanced environmental characteristics. This method can be a potential alternative for users seeking materials that could be effective at supporting a full sustainable development.