An improved synthesis of phenylene-bridged methylated binuclear ferrocene

Yavaraja Dibdalli, Cristian Valdebenito, Mungalimane K. Amshumali, Elies Molins, Cesar Morales-Verdejo

Abstract

This contribution describes an updated synthetic route along with full characterization of [{CpFe} 2-p-Ph’] with p-Ph’: p-Bis {2, 3, 4, 5-tetramethylcyclopentadienyl} benzene). The complex reported here was characterized by 1 H and 13 C NMR, elemental analysis, the X-ray crystal structure, and Mo? ssbauer spectroscopy. From the crystallographic analysis, it was found that both {CpFe} fragments are coordinated to opposite sites of the p-Ph’ligand. In addition, the analysis through of 1 H and 13 C NMR spectroscopy, confirm that the synthesis and yield of just one isomer of this compound.

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Título de la Revista: JOURNAL OF THE CHILEAN CHEMICAL SOCIETY
Volumen: 67
Editorial: 2013
Fecha de publicación: 2022
Página de inicio: 5414
Página final: 5417
URL: https://www.scielo.cl/scielo.php?pid=S0717-97072022000105414&script=sci_arttext