Oxidative degradations of the side chain of unsaturated Ent-labdanes. Part I.

Catalan, LE; Altamirano, HC; Fritis, MC; Araya, CG; Mari, KC

Abstract

A selective route for the degradation of the unsaturated side chain of ent-labdanes has been devised, giving two useful synthons: 2β-acetoxy-14, 15,17-trinor-ent-labdane-8,13-dione (5) and 2β-acetoxy-14,15-dinor-ent- labd-8(17)-en-13-one (7), the use of which for the preparation of terpenylquinone derivatives shall be reported elsewhere. © 2007 by MDPI.

Más información

Título según WOS: Oxidative degradations of the side chain of unsaturated Ent-labdanes. Part I.
Título según SCOPUS: Oxidative degradations of the side chain of unsaturated Ent-labdanes. Part I
Título de la Revista: MOLECULES
Volumen: 12
Número: 3
Editorial: MDPI
Fecha de publicación: 2007
Página de inicio: 318
Página final: 327
Idioma: English
URL: http://www.mdpi.com/1420-3049/12/3/318/
DOI:

10.3390/12030318

Notas: ISI, SCOPUS