Abstract

Recently, we reported a series of global minima whose structures consist of carbon rings decorated with heavier group 14 elements. Interestingly, these structures feature planar tetracoordinate carbons (ptCs) and result from the replacement of five or six protons (H+) from the cyclopentadienyl anion (C5H5-) or the pentalene dianion (C8H62-) by three or four E2+ dications (E = Si-Pb), respectively. The silicon derivatives of these series are the Si3C5 and Si4C8 clusters. Here we show that ptC persists in some clusters with an equivalent number of C and Si atoms, i.e., Si5C5, Si8C8, and Si9C9. In all these species, the ptC is embedded in a pentagonal C-5 ring and participates in a three-center, two-electron (3c-2e) Si-ptC-Si sigma-bond. Furthermore, these clusters are 7-t-aromatic species according to chemical bonding analysis and magnetic criteria.