Article ISI
CHEMICAL COMMUNICATIONS  (2024)

Anti-electrostatic cation⋯π-hole and cation⋯lp-hole interactions are stabilized via collective interactions

Pino-Rios, Ricardo; Baez-Grez, Rodrigo; Foroutan-Nejad, Cina

Abstract

Collective interactions are a novel type of bond between metals and AX(3) fragments with an electropositive central atom, A, and electronegative X substituents. Here, using electrostatic potential maps and state-of-the-art bonding analysis tools we have shown that collective interactions are anti-electrostatic cation & ctdot;pi-Hole or cation & ctdot;lp-Hole interactions.

Más información

Título según WOS: Anti-electrostatic cation⋯π-hole and cation⋯lp-hole interactions are stabilized via collective interactions
Título de la Revista: CHEMICAL COMMUNICATIONS
Volumen: 60
Número: 4
Editorial: ROYAL SOC CHEMISTRY
Fecha de publicación: 2024
Página de inicio: 400
Página final: 403
DOI:

10.1039/d3cc05451a
Notas: ISI