A triclinic modification of 5,5 '-dinitro-2,2 '-dithiodipyridine

Brito, I; Mundaca, A; Cardenas, A; Lopez-Rodriguez, M

Abstract

The asymmetric unit of the title compound, C10H6N4O4S2, contains two independent but similar mol-ecules. The structure is a triclinic polymorph of the monoclinic structure reported previously [Brito, Mundaca, Cárdenas, López-Rodríguez & Vargas (2007). Acta Cryst. E63, o3351-o3352]. The most obvious difference between the two polymorphs is the C - S - S - C torsion angle [-80.13 (16), -79.8 (2) and 0° for the two mol-ecules of the triclinic polymorph and the monoclinic polymorph, respectively]. The crystal structure of the title compound has two intra-molecular C - H⋯S inter-actions with average H⋯S distances of 2.69 Å, whereas this kind of inter-action is not evident in the monoclinic polymorph. © International Union of Crystallography 2008.

Más información

Título según WOS: A triclinic modification of 5,5 '-dinitro-2,2 '-dithiodipyridine
Título según SCOPUS: A triclinic modification of 5,5'-dinitro-2,2'-dithio-dipyridine
Título de la Revista: ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
Volumen: 64
Número: 1
Editorial: WILEY-BLACKWELL
Fecha de publicación: 2008
Página de inicio: O102
Página final: U3419
Idioma: English
URL: http://scripts.iucr.org/cgi-bin/paper?S1600536807062630
DOI:

10.1107/S1600536807062630

Notas: ISI, SCOPUS