Abstract

The selectivities of the K-Ca and K-Mg cation exchange reactions were studied in batch experiments carried out with 7 Chilean saline sandy soils with low organic matter (OM) content, and rich in quartz and halite, by using the experimental Gaines and Thomas procedure and the semi-empirical Rothmund-Kornfeld approach. The soils present high reactivity to the exchange process in terms of CEC and a preference order from the surface for the cation of K>Ca>Mg. In addition, the existence of different types of exchange sites was determined; some were specific for determined cations and others presented free competition. The proposed exchange reaction for both equilibria was thermodynamically possible and the studied cations presented a decreasing mobility order K>Ca>Mg, which follows the increasing order of hydrated ionic radii. As for the Rothmund-Kornfeld semi-empirical approach, it can be employed on soils classified as Aridisol due to good fit with the experimental data. On the other hand, the Gaines and Thomas approach is only experimentally applicable since poses some restrictions concerning to salinity and carbonate contents in the studied soils. © CSIRO 2008.