Abstract

A mesoporous material was synthesized using silica extracts from fly ash and its properties were studied. Subsequently, it was functionalized with carbamoylmethylphosphine oxide (CMPO) to capture La 3+ and Ce 3+ . The developed mesoporous material was obtained by the sol-gel method and was called Si-MMS (siliceous mesoporous materials), subsequently functionalized with APTMS (1-(2-aminoethyl)-3-aminopropyl trimethoxysilane) in a reflux system, which led to the synthesis of Si-MMS-APTMS. This derivative was modified with carbonyldiimidazole (CDI) and diethylphosphonoacetic acid, which finally resulted in the synthesis of Si-MMS-CMPO as the final product. The materials were characterized by DRIFT, XRD, SEM-EDS, TEM, XPS, elemental analysis and nitrogen isotherms at -196 degrees C, confirming that the synthesis and subsequent modification of the mesoporous structure was successful. Adsorption studies in batch systems indicated that the optimal pH for La 3+ was 6, the Langmuir isotherm model and the non-linear Sips models were perfectly fitted and the best fitting kinetics is the Elovich model. For Ce 3+ the optimal pH was 7.5, the non-linear Sips isotherm fit the best and the non-linear Pseudo -second order kinetics was the mechanism that best represents the adsorption. The maximum experimental adsorption capacity q e of La 3+ was 17.00 mg g -1 and for Ce 3+ was 30.09 mg g -1 . In both cases, the rapid adsorption suggests an open porous matrix that facilitates the formation of chelates between the adsorbates and the phosphoryl group -PO 3 2- .