8-(DIMETHYLAMINO)-N,N-DIMETHYLNAPHTHALEN-1-AMINIUM AND HYDROGENTEREPHTHALATE AS SYNTHONS FOR SUPRAMOLECULAR ARCHITECTURE
Abstract
8-(dimethylamino)-N,N-dimethylnaphthalen-1-aminium hydrogenterephthalate (PSH+TPAH-) and 8-(dimethylamino)-N,N-dimethylnaphthalen-1-aminium hydrogen-terephthalate hydrate (PSH+TPAH-·H2O) were prepared by the direct reaction of N1,N1,N8,N8-tetramethylnaphthalene-1,8-diamine, Proton Sponge (PS) © and terephthalic acid (TPAH2) in a 1:1 stoichiometric relation. The structure of both salts is constructed on the base of 1D chains defined by hydrogen bonding of the anionic carboxylate end and the carboxylic acid of TPAH- anion. Additionally for the structure of PSH+TPAH-·H2O the water molecules connect this 1D chains through hydrogen bonds, then defining a 1D-belt. In both cases the PSH+ provides balance of charge among the chains.
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Título de la Revista: | Journal of the Chilean Chemical Society |
Volumen: | 68 |
Editorial: | 2013 |
Fecha de publicación: | 2023 |
Página de inicio: | 5745 |
Página final: | 5747 |
URL: | https://www.jcchems.com/index.php/JCCHEMS/article/view/2163 |