A new dual probe for hydrogen abstraction

Aliaga C.; Rezende, MC; Tirapegui, C.

Abstract

A new dual (fluorescent and spin) probe is described, where a N-aryl-2,4,6-triphenylpyridinium fluorophore is attached to a TEMPO fragment through an amide link. The resulting sensor 4 was evaluated as a hydrogen-abstracting agent in acetonitrile and in an aqueous solution of reduced Triton-X 100, being as resistant to hydrolysis as quinoline-TEMPO 1, but more hydrophobic than this probe. © 2009 Elsevier Ltd. All rights reserved.

Más información

Título según WOS: A new dual probe for hydrogen abstraction
Título según SCOPUS: A new dual probe for hydrogen abstraction
Título de la Revista: TETRAHEDRON
Volumen: 65
Número: 31
Editorial: PERGAMON-ELSEVIER SCIENCE LTD
Fecha de publicación: 2009
Página de inicio: 6025
Página final: 6028
Idioma: English
URL: http://linkinghub.elsevier.com/retrieve/pii/S0040402009008114
DOI:

10.1016/j.tet.2009.05.073

Notas: ISI, SCOPUS