A new dual probe for hydrogen abstraction
Abstract
A new dual (fluorescent and spin) probe is described, where a N-aryl-2,4,6-triphenylpyridinium fluorophore is attached to a TEMPO fragment through an amide link. The resulting sensor 4 was evaluated as a hydrogen-abstracting agent in acetonitrile and in an aqueous solution of reduced Triton-X 100, being as resistant to hydrolysis as quinoline-TEMPO 1, but more hydrophobic than this probe. © 2009 Elsevier Ltd. All rights reserved.
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Título según WOS: | A new dual probe for hydrogen abstraction |
Título según SCOPUS: | A new dual probe for hydrogen abstraction |
Título de la Revista: | TETRAHEDRON |
Volumen: | 65 |
Número: | 31 |
Editorial: | PERGAMON-ELSEVIER SCIENCE LTD |
Fecha de publicación: | 2009 |
Página de inicio: | 6025 |
Página final: | 6028 |
Idioma: | English |
URL: | http://linkinghub.elsevier.com/retrieve/pii/S0040402009008114 |
DOI: |
10.1016/j.tet.2009.05.073 |
Notas: | ISI, SCOPUS |