Abstract

We investigate the collective non-Markovian dynamics of two fully excited two-level atoms coupled to a one-dimensional waveguide in the presence of delay. We demonstrate that analogous to the well-known superfluorescence phenomena, where an inverted atomic ensemble synchronizes to enhance its emission, there is a "subfluorescence" effect that synchronizes the atoms into an entangled dark state depending on the interatomic separation. The phenomenon can lead to a two-photon bound state in the continuum. Our results are pertinent to long-distance quantum networks, presenting a mechanism for spontaneous entanglement generation between distant quantum emitters.