Hierarchical nanoengineered NiCo LDH@α-Fe2O3 heterostructures for optimised electrochemical capacitive performance

Rangaraju, Hariprasath; Matheswaran, Priyadharshini; Govindasamy, Mani; Parasuraman, Balaji; Shanmugaraj, Krishnamoorthy; Thangavelu, Pazhanivel

Abstract

High necessity of designing high performance energy storage device with better class of materials having high specific energy and specific power have gained much attention due to its peak demand. Herein, a hybrid composite containing NiCo layered double hydroxide with hematite (alpha-Fe2O3) was prepared in single pot solvothermal technique. alpha-Fe2O3 was combined with NiCo LDH to alter its interlayer spacing, and increase electro active sites for better charge transfer kinetics. Such designed nanoarchitectonics have been employed as a cathode material for supercapacitors. The electrode tested in half-cell configuaration has outsmarted other pristine materials with a high specific capacitance of 1811 F/g at 1 A/g and better cyclic stability (82 % after 5000 cycles). In addition, a hybrid device was fabricated using NiCo LDH/alpha-Fe2O3(2:1) and CAC as cathode and anode has displayed a high specific energy of 63.64 Wh/Kg at a specific power of 749 W/kg with good cyclic efficiency of 85 % after 10000 cycles. The obtained results proposes that the optimised NiCo LDH/alpha-Fe2O3 based composite as a potential candidate for electrode materials in supercapacitors.

Más información

Título según WOS: ID WOS:001468965700001 Not found in local WOS DB
Título de la Revista: MATERIALS CHEMISTRY AND PHYSICS
Volumen: 340
Editorial: ELSEVIER SCIENCE SA
Fecha de publicación: 2025
DOI:

10.1016/j.matchemphys.2025.130822

Notas: ISI