Article ISI SCOPUS
INORGANIC CHEMISTRY COMMUNICATIONS  (2010)

Synthesis, structure and catalytic activities for hydrogen transfer reaction of the carbonyl ruthenium(II) complex containing polypyridine and phosphine ligands

Moya, SA; Vidal, M.,; Abarca G.; Martínez C; Guerchais, V; Le Bozec, H; Garland, MT; Rodríguez, S.; Aguirre P.

Abstract

The synthesis and characterization of new ruthenium(II) carbonyl complexes containing polypyridine and triphenylphosphine ligands is reported. Crystallographic information obtained for the trans-PPh3-[Ru(biq) (PPh3)2(CO)]Cl2 complex (biq = 2,2'-biquinoline) reveals five-coordination on the metal. The complexes were studied as catalysts in hydrogen transfer reactions in basic solution. Turnover frequencies in the 2250-817 h-1 range were determined in 1 hour of reaction with a substrate/catalysts ratio of 830. © 2010 Elsevier B.V. All rights reserved.

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Título según WOS: Synthesis, structure and catalytic activities for hydrogen transfer reaction of the carbonyl ruthenium(II) complex containing polypyridine and phosphine ligands
Título según SCOPUS: Synthesis, structure and catalytic activities for hydrogen transfer reaction of the carbonyl ruthenium(II) complex containing polypyridine and phosphine ligands
Título de la Revista: INORGANIC CHEMISTRY COMMUNICATIONS
Volumen: 13
Número: 12
Editorial: Elsevier
Fecha de publicación: 2010
Página de inicio: 1519
Página final: 1521
Idioma: English
DOI:

10.1016/j.inoche.2010.09.001
Notas: ISI, SCOPUS