Abstract

This manuscript describes a novel reactivity descriptor for Fe phthalocyanines molecular catalysts confined on the surface of OPG electrodes. The descriptor ?E°’cat. is the gap in potential between the E°Fe(III)/(II) and E°Fe(II)/(I) redox processes for each FeN4 catalyst. This descriptor, labeled as the electrochemical hardness ?E°’cat. Was examined using FeN4 macrocyclic complexes for the electrooxidation of 2-mercaptoethanol (2-ME) and thioglycolic acid TGA. Our findings reveal that the reactivity as log log(j/?)E, plotted versus E°Fe(III)/(II) or E°Fe(II)/(I) give two linear correlations. The activity log(j/?)E in both cases decreases with the redox potential of each FeN4 catalyst. In contrast log(j/?)E, or log (TOF)E, increase with ?E°’cat.. The Fe[sbnd]S binding energy ?E°’cat. Correlates linearly with ?E°’cat. so the softer the system the greater the binding energy and the lower the catalytic activity. © 2024