Eco-friendly synthesis and evaluation of copper-iron based electrocatalytic nanomaterials obtained from mine tailings for oxygen evolution reaction: Towards a cleaner and more sustainable energy

Carmona, Erico R.; Saraiva, Douglas Philip Martinez; Nelson, Ronald; Bertotti, Mauro; Hernandez-Saravia, Lucas Patricio

Abstract

Copper ore tailings contain significant amounts of iron and copper, which, given their abundance, must be exploited comprehensively. This study presents an eco-friendly synthesis of copper ferrite nanoparticles (CuFe2O4) using mango peel extract, focusing on their application for the oxygen evolution reaction (OER). The resulting nanoparticles, characterized by various analytical techniques, show a distinctive spherical morphology with a high surface area, demonstrating excellent electrocatalytic activity in alkaline media. With mean crystallite of 36 +/- 3 nm size, these nanoparticles reached a current density of 10 mA cm-2 at a low overpotential of 0.216 V, showing good durability and stability. The high OER activity is attributed to the unique morphology, which provides a large surface area and a porous structure ideal for the adsorption and activation of reactive species. Additionally, structural defects facilitate the migration of these species and the electron transfer, accelerating the OER reaction.

Más información

Título según WOS: ID WOS:001680181900001 Not found in local WOS DB
Título de la Revista: JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
Volumen: 14
Número: 2
Editorial: ELSEVIER SCI LTD
Fecha de publicación: 2026
DOI:

10.1016/j.jece.2026.121456

Notas: ISI