Infrared spectrum of the bis-(1,10-phenanthroline) Cu(I) and Cu(II) perchlorate complexes

Campos-Vallette M.M.; Clavijo, R.E.; Mendizabal, F; Zamudio W.; Baraona R.; Diaz G.

Abstract

FT-IR spectra of the title compounds and derivatives were measured in the range 4000-120 cm -1. A complete experimental spectral assignment has been performed. A simplified normal coordinate treatment orientates some assignment of frequencies in the low energy region. Bands at ca. 420 and 300 cm -1 are ascribed to the ?Cu-N modes. A stability order of the Cu(I) complexes is proposed on the basis of their Cu-N frequency values.

Más información

Título de la Revista: VIBRATIONAL SPECTROSCOPY
Volumen: 12
Número: 1
Editorial: ELSEVIER SCIENCE BV
Fecha de publicación: 1996
Página de inicio: 37
Página final: 44
URL: http://www.scopus.com/inward/record.url?eid=2-s2.0-0002324180&partnerID=q2rCbXpz