Article
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS  (1996)

Dichloro(di-2-pyridylamine-N,N?)copper(II)

Spodine, E.; Atria A.M.; Baggio R.; Garland M.T.

Keywords: copper, dynamics, derivatives, ions, atoms, interactions, pyridine, molecular, monomers, organometallics, cation, chlorine, compounds, Dichlorodipyridylaminecopper, Intramolecular, Tetrahedron

Abstract

The title complex, [CuCl2(C10H9N3)], is a monomer, with the Cu atom in a rather distorted tetrahedral environment provided by two Cl- ions and two N atoms from the bidentate bipyridine derivative. The group is bisected by a twofold axis passing through the cation and the amine N atom bridging the symmetry-related pyridine groups. The deformation of the coordination tetrahedron is due to the Cl- ion taking part in intramolecular interactions.

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Título de la Revista: ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
Volumen: 52
Número: 6
Editorial: WILEY-BLACKWELL PUBLISHING, INC
Fecha de publicación: 1996
Página de inicio: 1407
Página final: 1410
URL: http://www.scopus.com/inward/record.url?eid=2-s2.0-0030164154&partnerID=q2rCbXpz